So diving down the oul' internet rabbit hole, as I tend to do...
The previous owner had actually posted up elsewhere about this issue a few weeks prior to him selling it. (Again, he did disclose this issue, so not claiming he sold me a faulty machine. Well, he did - but did so openly, and I bought it knowing it!) Per him:
In PAL hires, lores, interlaced, super hires etc. The grey has a brown tint to it (pic on left). Not the same as my A600 or A500. However, if I choose productivity or dblpal then I get the nice pure grey (pic on right) I’m expecting. Photos were taken from an lcd via an Amiga video out to ossc but the results are same using a scart lead straight into a commodore 1081 monitor. Any idea what might be causing this?
Also the palette colour for the grey background is set to 170/170/170 in all instances so it's not that. Also my A500 and A600 were tested using the same cables and are fine.
EDIT: Same off colour tint on the composite output as well (can only try the PAL modes I guess on this; DBLPAL the monitor didn't like)
So does indeed replicate in composite. I pulled out the multimeter and checked the RGB resistors (R232A/B/C and R231A/B/C) which showed all six were the correct values (25ohm for R232 and 50 for R231) so don't THINK they're the issue, although obitus' point about a bad trace could also be an issue. (Board looks GREAT tho, recapped by Retropassion on 10/20 so just six months ago... which makes me think its a recent happening, since surely he'd have seen that in testing after the recap). Looking at this video here,
https://www.youtube.com/watch?v=8xlG9Ln5o30
Does make me worry about the Video DAC. (And others have said the same thing.) So from my completely idiotic standpoint, the original diagnosis LOOKS to be close to the mark, and that its a $5 chip plus labour. (Or it could be something else entirely. I can cobble together breadboards, but when it comes to actual boards then I'm WAY over my head!)